Pain’s assault on the Hidden Leaf Village plays out during season 8 after he silenced Jiraiya — a legendary Sannin and Naruto’s mentor — and the arc officially wraps by episode 176.
Watch Naruto Shippuden: Season 17 Itachi's Story - Light and Darkness: The Pain of Living, on Crunchyroll. Upon graduating from the Academy, Itachi becomes a genin and joins a team that includes
Naruto Vs Pain English Dub - HD PLEASE READ:I don't own anything in the video, including the audio and picture. The credits go to the respective owners. Thi Either way, they are well worth a watch. 25. Eye To Eye: Sharingan VS Sharingan! (8.4) Masashi Kishimoto. This episode establishes Itachi Uchiha as a formidable threat to Konoha in the "Naruto While Naruto is full of epic battles, one of the most memorable ones is the confrontation between Naruto and Pain in the ruins of the destroyed Konohagakure village.That fight is so good and rewarding in terms of overall storytelling that the actual final battle of the series, the huge Fourth Shinobi World War, feels like a drag, proving that the manga should have ended much earlier.

The first path of Pain that is seen in the anime is in episode 128. Pain appears in Naruto shippuuden episode 16 in a jutsu. Naruto fights pain in six episodes. In naruto shippuden episode 163-168

Also it's Pain's fault to perform that speech to Naruto instead of knocking him, and to torture Hinata in front of Naruto. Pain was too confident in his deva path and he was carried away by many feelings (His revenge against Konoha, Naruto being Jiraiya's last disciple, and Naruto being like he used to be when Yahiko was still alive) that
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    • pain vs naruto which episode